E I DUPONT DE NEMOURS & CO INC -- KROVAR II DF HERBICIDE, M0000032 -- 6840-00N015283
===================== Product Identification ===================== Product ID:KROVAR II DF HERBICIDE, M0000032 MSDS Date:02/01/1988 FSC:6840 NIIN:00N015283 === Responsible Party === Company Name:E I DUPONT DE NEMOURS & CO INC Address:1007 MARKET STREET City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-7515 Emergency Phone Num:800-441-3637;800-424-9300(CHEMTREC) CAGE:0ERJ7 === Contractor Identification === Company Name:E I DUPONT DE NEMOURS & CO, INC. Address:1007 MARKET STREET City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515 CAGE:0ERJ7 Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:ING 13: CONDUCTED AT HASKELL LAB, BROMACIL HAS BEEN RPTD TO BE NON-MUTAGENIC IN 5 OF 6 PT/GENE MUTATION (SEE ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: STUDIES, 6 OF 6 PRIMARY DNA DMG STUDIES & 3 OF 4 TESTS FOR CHROMOSOMAL EFTS. DIURON: THE CMPD IS (SEE ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: A SKIN IRRITANT, IS AN EYE IRRITANT, & IS NOT A SKIN SENSIT IN ANIMALS. TOXIC EFTS DESCRIBED IN (SEE ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: ANIMALS FROM SHORT EXPOS BY INHAL, INGEST/SKIN CONT INCL: BLOOD EFTS, SPLEEN EFTS, THYROID EFTS, (SEE ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: METHEMOGLOBINEMIA, & NONSPECIFIC EFTS SUCH AS WEIGHT LOSS & IRRIT. TESTS IN SOME ANIMALS INDICATE (SEE ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: THAT THE CMPD MAY HAVE EMBRYOTOXIC ACTIVITY. ANIMAL TESTING INDICATES THAT THIS CMPD DOES NOT HAVE (SEE ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: MUTAGENIC/REPRO EFTS. HUMAN HLTH EFTS OF OVEREXP BY INHAL, INGEST/SKIN/EYE CONT MAY INITIALLY INCL: (SEE ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: SKIN IRRIT W/DISCOMFORT/RASH; EYE IRRIT W/DISCOMFORT, TEARING/BLURRING OF VISION; LIVER ENLARGEMENT;(SEE ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: SPLEEN & THYROID EFTS; RED BLOOD CELL DESTRUCTION;/REDUCTION OF BLOOD'S OXYGEN CARRYING CAPACITY W/ (SEE ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: CYANOSIS (BLUISH DISCOLORATION), WEAKNESS/SHORTNESS OF BREATH BY FORMATION OF METHEMOGLOBIN. (SEE ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: SIGNIFICANT SKIN PERMEATION AFTER CONT APPEARS UNLIKELY. THERE ARE NOT RPTS OF HUMAN SENSIT. RTECS #:9999999ZZ Ingred Name:BROMACIL CAS:314-40-9 RTECS #:YQ9100000 Fraction by Wt: 53% OSHA PEL:1 PPM ACGIH TLV:10 MG/M3; 9192 Ingred Name:DIURON (SARA III) CAS:330-54-1 RTECS #:YS8925000 Fraction by Wt: 27% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:INERT INGREDIENTS Fraction by Wt: 20% Ingred Name:HNDLG/STOR PREC: DO NOT STORE WITH OTHER PESTICIDES, FERTILIZER, FOOD OR FEED. SUPP DATA: STATISTICALLY (SEE ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: SIGNIFICANT INCR IN TOTAL LIVER TUMORS WAS SEEN IN MALE MICE ONLY. NEITHER CARCINOMAS NOR ADENOMAS (SEE ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: CONSIDERED SEPARATELY WERE STATISTICALLY SIGNIFICANT, NOR WERE USUAL TUMOR TYPES NOTED. STATISTICALLY (SEE ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: SIGNIFICANT INCREASES IN NATURALLY OCCURING, NON-NEOPLASTIC TESTICULAR LESIONS WERE SEEN AT ALL (SEE ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: MALE TREATMENT LEVELS, AND IN LIVER LESIONS AT ALL MALE & ONLY THE HIGHEST FEMALE TREATMENT GROUPS. (SEE ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: DOG FEEDING STUDY: IN A 24-MONTH STUDY 0, 50, 250, AND 1250 PPM, NO NUTRITIONAL, CLINICAL, (SEE ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: HEMATOLOGICAL, URINARY, BIOCHEMICAL/PATHOLOGICAL EVIDENCE OF TOXICITY WAS OBSERVED IN ANY TEST GP. (SEE ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: REPRO (RATS): DIETARY ADMIN OF 0 & 250 PPM BROMACIL DID NOT AFFECT NORMAL REPRO/LACTATION IN A (SEE ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: 3-GENERATION, 6 LITTER REPRO STUDY. TERATONGENICITY: RBTS WERE FED 0, 50, & 250 PPM BROMACIL IN (SEE ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: DIET. BROMACIL WAS NEITHER EMBRYOTOXIC NOR TERATOGENIC AT ANY LEVEL. MUTAGENICITY: IN STUDIES NOT (SEE ING 14) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE HEALTH HAZARDS Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CAUTION! HARMFUL IF SWALLOWED. CAUSES MOD EYE INJURY. ACUTE ORAL (RTS): LD50 IS 2,300 MG/KG (MALE); 1,300 MG/KG (FEMALES). SLIGHTLY TOXIC BY INGEST. ACUTE DERM (RBTS): LD50 >2,000 MG/KG. SLIGHTLY TO M OD TOXIC BY CONT. NOT A PRIMARY SKIN IRRITANT. NOT A SKIN SENSITIZER. EYE: MOD IRRITANT. CORNEAL (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: OPACITY & OTHER EFTS PRESENT AT FOUR DAYS AFTER TREATMENT. ALL EFTS REVERSED WITHIN 7 DAYS. (CHRONIC) BROMACIL: RAT FEEDING STUDY: IN A 24-MONTH STUDY AT 0, 50, 250 & 1250 PPM, NO CLINICAL, HEMATOLOGICAL, URINARY, OR BIOCHEMICAL EVIDENCE OF TOXICITY WAS OBSERVED IN THE TEST GROUPS. AT HIGHEST (SEE SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN: FLUSH W/WATER. EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. CAL L MD. INGEST: INDUCE VOMIT IMMED BY GIVING TWO GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCONS PERSON. CALL MD. ===================== Fire Fighting Measures ===================== Lower Limits:0.135 G/L Extinguishing Media:WATER SPRAY, CHEMICAL FOAM, DRY CHEMICAL & CO*2. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY. COOL TANK/CONTAINER WITH WATER SPRAY. Unusual Fire/Explosion Hazard:DUST FORMS EXPLO MIXT W/AIR. IF AREA IS HEAVILY EXPSD TO FIRE & IF CNDTNS PERMIT, LET FIRE BURN ITSELF OUT SINCE WATER MAY INCR CONTAMINATION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:REVIEW FIRE & EXPLO HAZ & SAFETY PREC BEFORE PROCEEDING W/CLEAN UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN UP. SHOVEL/SWEEP UP. IF SPILL AREA IS ON GROUND NEAR VALUABLE PLANTS/TREES, REMOVE TOP 2 INCHES OF SOIL AFTER INITIAL CLEANUP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL VENT AREA. KEEP CNTNR TIGHTLY CLSD. DO NOT STORE/CONSUME FOOD, DRINK/TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAM W/MATL. (SEE ING 4) Other Precautions:AVOID BREATHING VAPORS OR MIST. AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN, OR CLOTHING. AVOID DUST GENERATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE ONLY WITH ADEQUATE VENTILATION. Protective Gloves:NONE SPECIFIED BY MANUFACTURER. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH CLOTHING AFTER USE. Supplemental Safety and Health EFTS OF OVEREXP: LEVEL, SLIGHT BODY WEIGHT RETARDATION WAS SEEN IN FEMALES & THYROID EFTS WERE SEEN IN MALES & FEMALES. THE NO-EFT LEVEL WAS 250 PPM. NO ONCOGENIC EFTS WERE SEEN AT ANY LEVEL. (MICE): IN AN 18-MONTH FEEDING STUDY, MICE WEREFED 0, 250, 1,250, OR 5,000 PPM BROMACIL. AT HIGHEST RATE, A (SEE ING 4) ================== Physical/Chemical Properties ================== pH:7.4@2% Solubility in Water:DISPERSIBLE Appearance and Odor:SOLID IVORY WITH NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DECOMPOSES WITH HEAT. ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.